New Catalysis Breakthrough Could Unlock Massive Energy Savings

Energy Conversion Abstract

University of Wisconsin-Madison chemical engineers have made a breakthrough in computational chemistry by developing a model of catalytic reactions at the atomic scale. This new understanding could lead to more efficient catalysts, tuned industrial processes, and significant energy savings, as catalysis plays a crucial role in producing 90% of the products we encounter in our lives.

In a significant breakthrough for the field of computational chemistry, chemical engineers from the University of Wisconsin-Madison have created a model that elucidates how catalytic reactions work at the atomic level. This newfound understanding could enable engineers and chemists to design improved catalysts and optimize industrial procedures, possibly resulting in enormous energy savings, as catalysis is involved in the production of 90% of the products we use daily.

Lang Xu

Lang Xu. Credit: University of Wisconsin–Madison

Catalyst substances accelerate chemical reactions without undergoing changes themselves. They play a crucial role in processing petroleum products and producing a wide array of items, including pharmaceuticals, plastics, food additives, fertilizers, eco-friendly fuels, and various industrial chemicals.

Scientists and engineers have spent decades fine-tuning catalytic reactions — yet because it’s currently impossible to directly observe those reactions at the extreme temperatures and pressures often involved in industrial-scale catalysis, they haven’t known exactly what is taking place on the nano and atomic scales. This new research helps unravel that mystery with potentially major ramifications for industry.

In fact, just three catalytic reactions — steam-methane reforming to produce hydrogen, ammonia synthesis to produce fertilizer, and methanol synthesis — use close to 10% of the world’s energy.

“If you decrease the temperatures at which you have to run these reactions by only a few degrees, there will be an enormous decrease in the energy demand that we face as humanity today,” says Manos Mavrikakis, a professor of chemical and biological engineering at UW–Madison who led the research. “By decreasing the energy needs to run all these processes, you are also decreasing their environmental footprint.”

Mavrikakis and postdoctoral researchers Lang Xu and Konstantinos G. Papanikolaou along with graduate student Lisa Je published news of their advance in the April 7, 2023 issue of the journal Science.

Mano Mavrikakis

Mano Mavrikakis. Credit: University of Wisconsin–Madison

In their research, the UW–Madison engineers develop and use powerful modeling techniques to simulate catalytic reactions at the atomic scale. For this study, they looked at reactions involving transition metal catalysts in nanoparticle form, which include elements like platinum, palladium, rhodium, copper, nickel, and others important in industry and green energy.

According to the current rigid-surface model of catalysis, the tightly packed atoms of transition metal catalysts provide a 2D surface that chemical reactants adhere to and participate in reactions. When enough pressure and heat or electricity is applied, the bonds between atoms in the chemical reactants break, allowing the fragments to recombine into new chemical products.

“The prevailing assumption is that these metal atoms are strongly bonded to each other and simply provide ‘landing spots’ for reactants. What everybody has assumed is that metal-metal bonds remain intact during the reactions they catalyze,” says Mavrikakis. “So here, for the first time, we asked the question, ‘Could the energy to break bonds in reactants be of similar amounts to the energy needed to disrupt bonds within the catalyst?’”

According to Mavrikakis’s modeling, the answer is yes. The energy provided for many catalytic processes to take place is enough to break bonds and allow single metal atoms (known as adatoms) to pop loose and start traveling on the surface of the catalyst. These adatoms combine into clusters, which serve as sites on the catalyst where chemical reactions can take place much easier than the original rigid surface of the catalyst.

Using a set of special calculations, the team looked at industrially important interactions of eight transition metal catalysts and 18 reactants, identifying energy levels and temperatures likely to form such small metal clusters, as well as the number of atoms in each cluster, which can also dramatically affect reaction rates.

Their experimental collaborators at the University of California, Berkeley, used atomically-resolved scanning tunneling microscopy to look at carbon monoxide adsorption on nickel (111), a stable, crystalline form of nickel useful in catalysis. Their experiments confirmed models that showed various defects in the structure of the catalyst can also influence how single metal atoms pop loose, as well as how reaction sites form.

Mavrikakis says the new framework is challenging the foundation of how researchers understand catalysis and how it takes place. It may apply to other non-metal catalysts as well, which he will investigate in future work. It is also relevant to understanding other important phenomena, including corrosion and tribology, or the interaction of surfaces in motion.

“We’re revisiting some very well-established assumptions in understanding how catalysts work and, more generally, how molecules interact with solids,” Mavrikakis says.

Reference: “Formation of active sites on transition metals through reaction-driven migration of surface atoms” by Lang Xu, Konstantinos G. Papanikolaou, Barbara A. J. Lechner, Lisa Je, Gabor A. Somorjai, Miquel Salmeron Manos Mavrikakis, 6 April 2023, Science.
DOI: 10.1126/science.add0089

The authors acknowledge support from the U.S. Department of Energy, Basic Energy Sciences, Division of Chemical Sciences, Catalysis Science Program, Grant DE-FG02-05ER15731; the Office of Basic Energy Sciences, Division of Materials Sciences and Engineering, of the U.S. Department of Energy under contract no. DE-AC02-05CH11231, through the Structure and Dynamics of Materials Interfaces program (FWP KC31SM).

Mavrikakis acknowledges financial support from the Miller Institute at UC Berkeley through a Visiting Miller Professorship with the Department of Chemistry.

The team also used the National Energy Research Scientific Computing Center, a DOE Office of Science User Facility supported by the Office of Science of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231 using NERSC award BES- ERCAP0022773.

Part of the computational work was carried out using supercomputing resources at the Center for Nanoscale Materials, a DOE Office of Science User Facility located at Argonne National Laboratory, supported by DOE contract DE-AC02-06CH11357.

1 Comment on "New Catalysis Breakthrough Could Unlock Massive Energy Savings"

  1. Frosted Flake | April 9, 2023 at 5:53 pm | Reply

    Elucidates = clarifies.

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