Green Energy Breakthrough: Scientists Develop Catalyst With 7.9x Higher Activity for Hydrogen Production

Researchers have developed an advanced platinum nanocatalyst that significantly improves hydrogen production efficiency. This breakthrough hybrid catalyst showcased enhanced activity and stability, with potential applications for hydrogen-powered vehicles.

According to data from the Ministry of Land, Infrastructure, and Transport of Korea, there were approximately 30,000 hydrogen-powered vehicles registered by 2022, representing a threefold increase compared to 2018. However, the country only has 135 hydrogen fueling stations.

For hydrogen to be more accessible for vehicles and to be recognized as a reliable energy alternative, it’s essential to bring down the production costs of hydrogen, ensuring it’s economically viable. Central to this objective is optimizing the efficiency of the electrolysis-hydrogen evolution process, which produces hydrogen from water.

Breakthrough in Hydrogen Production

Recently, a team of researchers comprising Professor In Su Lee, Research Professor Soumen Dutta, and Byeong Su Gu from the Department of Chemistry at Pohang University of Science and Technology (POSTECH) achieved a significant improvement in the production efficiency of hydrogen, a green energy source, through the development of a platinum nanocatalyst.

Illustration of the mechanism of the three-metal hybrid nanocatalyst for hydrogen evolution. Credit: POSTECH

They accomplished this feat by depositing two different metals in a stepwise manner. The findings of their research were published in Angewandte Chemie, the esteemed journal that focuses on the field of chemistry.

Challenges and Innovation in Catalyst Development

Depositing distinct materials selectively on specific locations of a catalyst surface, whose size is in the nanometer range, poses substantial challenges. Unintended depositions may block the catalyst’s active sites or interfere with each other’s functions. This predicament has prevented the simultaneous deposition of nickel and palladium onto a single material. Nickel is responsible for activating water splitting while palladium facilitates the conversion of hydrogen ions into hydrogen molecules.

Diagram of the three-metal hybrid catalyst’s synthesis and hydrogen evolution. Credit: POSTECH

The research team developed a novel nanoreactor to finely control the location of metals deposited onto a 2D flat nanocrystal. Additionally, they devised a nano-scaled fine deposition process, enabling the coverage of different facets of the 2D platinum nanocrystal with different materials. This new approach led to the development of a “platinum-nickel-palladium” three-metal hybrid catalyst material achieved through consecutive depositions that selectively cover the flat surface and the edge of the 2D platinum nanocrystal with palladium and nickel nano thin films respectively.

Hybrid Catalyst’s Enhanced Efficiency

The hybrid catalyst featured distinct nickel/platinum and palladium/platinum interfaces positioned to facilitate the water splitting and hydrogen molecule generation processes respectively. Consequently, the collaborative occurrence of these two different processes significantly boosted the effectiveness of electrolysis-hydrogen evolution.

The research outcomes revealed that the three-metal hybrid nano catalyst exhibited a 7.9-fold increase in catalytic activity compared to the conventional platinum-carbon catalyst. Moreover, the novel catalyst demonstrated significant stability, maintaining its high catalytic activity even after a prolonged 50-hour reaction time. This resolved the issue of functional interferences or collisions between heterointerfaces. 

Closing Remarks from the Research Team

Professor In Su Lee who led the research expressed his optimism by stating, “We have successfully developed harmonious heterointerfaces formed on a hybrid material, overcoming the challenges of the process.” He further added, “I hope the research findings will find widespread application in the development of catalytic materials optimized for hydrogen reactions.”

Reference: “Harmonious Heterointerfaces Formed on 2D-Pt Nanodendrites by Facet-Respective Stepwise Metal Deposition for Enhanced Hydrogen Evolution Reaction” by Byeong Su Gu, Soumen Dutta, Yu-Rim Hong, Odongo Francis Ngome Okello, Hyeonae Im, Seungil Ahn, Si-Young Choi, Jeong Woo Han, Sunmin Ryu and In Su Lee, 19 June 2023, Angewandte Chemie International Edition.
DOI: 10.1002/anie.202307816

The study was conducted with the support from the Leading Researcher Program of the National Research Foundation of Korea.