Researchers Design a New Low Cost Lithium-Polysulfide Flow Battery

A new lithium-polysulfide flow battery design could enable solar and wind energy to become major suppliers to the electrical grid.

Researchers from the U.S. Department of Energy’s (DOE) SLAC National Accelerator Laboratory and Stanford University have designed a low-cost, long-life battery that could enable solar and wind energy to become major suppliers to the electrical grid.

“For solar and wind power to be used in a significant way, we need a battery made of economical materials that are easy to scale and still efficient,” said Yi Cui, a Stanford associate professor of materials science and engineering and a member of the Stanford Institute for Materials and Energy Sciences, a SLAC/Stanford joint institute. “We believe our new battery may be the best yet designed to regulate the natural fluctuations of these alternative energies.”

Cui and colleagues report their research results, some of the earliest supported by the DOE’s new Joint Center for Energy Storage Research battery hub, in the May issue of Energy & Environmental Science.

In this video, Stanford graduate student Wesley Zheng demonstrates the new low-cost, long-lived flow battery he helped create. The researchers created this miniature system using simple glassware. Adding a lithium polysulfide solution to the flask immediately produces electricity that lights an LED. A utility version of the new battery would be scaled up to store many megawatt-hours of energy. Credit: SLAC National Accelerator Laboratory

Currently the electrical grid cannot tolerate large and sudden power fluctuations caused by wide swings in sunlight and wind. As solar and wind combined contributions to an electrical grid approach 20 percent, energy storage systems must be available to smooth out the peaks and valleys of this “intermittent” power – storing excess energy and discharging when input drops.

Among the most promising batteries for intermittent grid storage today are “flow” batteries, because it’s relatively simple to scale their tanks, pumps, and pipes to the sizes needed to handle large capacities of energy. The new flow battery developed by Cui’s group has a simplified, less expensive design that presents a potentially viable solution for large-scale production.

Today’s flow batteries pump two different liquids through an interaction chamber where dissolved molecules undergo chemical reactions that store or give up energy. The chamber contains a membrane that only allows ions not involved in reactions to pass between the liquids while keeping the active ions physically separated. This battery design has two major drawbacks: the high cost of liquids containing rare materials such as vanadium – especially in the huge quantities needed for grid storage – and the membrane, which is also very expensive and requires frequent maintenance.

The new Stanford/SLAC battery design uses only one stream of molecules and does not need a membrane at all. Its molecules mostly consist of the relatively inexpensive elements lithium and sulfur, which interact with a piece of lithium metal coated with a barrier that permits electrons to pass without degrading the metal. When discharging, the molecules, called lithium polysulfides, absorb lithium ions; when charging, they lose them back into the liquid. The entire molecular stream is dissolved in an organic solvent, which doesn’t have the corrosion issues of water-based flow batteries.

“In initial lab tests, the new battery also retained excellent energy-storage performance through more than 2,000 charges and discharges, equivalent to more than 5.5 years of daily cycles,” Cui said.

To demonstrate their concept, the researchers created a miniature system using simple glassware. Adding a lithium polysulfide solution to the flask immediately produces electricity that lights an LED.

A utility version of the new battery would be scaled up to store many megawatt-hours of energy.

In the future, Cui’s group plans to make a laboratory-scale system to optimize its energy storage process and identify potential engineering issues, and to start discussions with potential hosts for a full-scale field-demonstration unit.

Reference: “A membrane-free lithium/polysulfide semi-liquid battery for large-scale energy storage” by Yuan Yang, Guangyuan Zheng and Yi Cui, 8 March 2013, Energy & Environmental Science.
DOI: 10.1039/C3EE00072A

Funding: US Department of Energy Joint Center for Energy Storage Research, US Department of Energy’s Office of Science, Stanford University

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