Citrus Derivative Makes Transparent Wood 100% Renewable

KTH researchers have created a high-strength, transparent wood using limonene acrylate from citrus waste. The eco-friendly material transmits light well and may lead to applications like heat-storing wood and smart lighting systems.

Since it was first introduced in 2016, transparent wood has been developed by researchers at KTH Royal Institute of Technology as an innovative structural material for building construction. It lets natural light through and can even store thermal energy.

The key to making wood into a transparent composite material is to strip out its lignin, the major light-absorbing component in wood. But the empty pores left behind by the absence of lignin need to be filled with something that restores the wood’s strength and allows light to permeate.

In earlier versions of the composite, researchers at KTH’s Wallenberg Wood Science Centre used fossil-based polymers. Now, the researchers have successfully tested an eco-friendly alternative: limonene acrylate, a monomer made from limonene. They reported their results in Advanced Science.

“The new limonene acrylate is made from renewable citrus, such as peel waste that can be recycled from the orange juice industry,” says lead author, PhD student Céline Montanari.

An extract from orange juice production is used to create the polymer that restores delignified wood’s strength and allows light to pass through.

The new composite offers optical transmittance of 90 percent at 1.2 mm thickness and remarkably low haze of 30 percent, the researchers report. Unlike other transparent wood composites developed during the past five years, the material developed at KTH is intended for structural use. It shows heavy-duty mechanical performance: with a strength of 174 MPa (25.2 ksi) and elasticity of 17 GPa (or about 2.5 Mpsi).

Sustainability as a Core Design Principle

Yet all along, sustainability has been a priority for the research group, says Professor Lars Berglund, the head of the KTH’s Department of Fibre and Polymer Technology.

“Replacing the fossil-based polymers has been one of the challenges we have had in making sustainable transparent wood,” Berglund says.

Environmental considerations and so-called green chemistry permeate the entire work, he says. The material is made with no solvents, and all chemicals are derived from bio-based raw materials.

The new advances could enable a yet unexplored range of applications, such as in wood nanotechnology, Berglund says. Possibilities include smart windows, wood for heat-storage, wood that has built-in lighting function – even a wooden laser.

Light Behavior and Aesthetic Effects

“We have looked at where the light goes, and what happens when it hits the cellulose,” Berglund says. “Some of the light goes straight through the wood, and makes the material transparent. Some of the light is refracted and scattered at different angles and gives pleasant effects in lighting applications.”

The team is also working with Sergei Popov’s photonics group at KTH to explore the nanotechnology possibilities even further.

Reference: “High Performance, Fully Bio‐Based, and Optically Transparent Wood Biocomposites” by Céline Montanari, Yu Ogawa, Peter Olsén and Lars A. Berglund, 2 May 2021, Advanced Science.
DOI: 10.1002/advs.202100559

Funding: Knut and Alice Wallenberg Foundation

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