Harvard Scientists Trilayer Graphene Breakthrough Opens the Door for High Temperature Superconductors

Twisted Trilayer Graphene

Artist rendition of twisted trilayer graphene. Credit: Polina Shmatkova & Margarita Davydova

In 2018, the physics world was set ablaze with the discovery that when an ultrathin layer of carbon, called graphene, is stacked and twisted to a “magic angle,” that new double layered structure converts into a superconductor, allowing electricity to flow without resistance or energy waste. Now, in a literal twist, Harvard scientists have expanded on that superconducting system by adding a third layer and rotating it, opening the door for continued advancements in graphene-based superconductivity.

The work is described in a new paper in Science and can one day help lead toward superconductors that operate at higher or even close to room temperature. These superconductors are considered the holy grail of condensed matter physics since they would allow for tremendous technological revolutions in many areas including electricity transmission, transportation, and quantum computing. Most superconductors today, including the double layered graphene structure, work only at ultracold temperatures.

“Superconductivity in twisted graphene provides physicists with an experimentally controllable and theoretically accessible model system where they can play with the system’s properties to decode the secrets of high temperature superconductivity,” said one of the paper’s co-lead authors Andrew Zimmerman, a postdoctoral researcher in working in the lab of Harvard physicist Philip Kim.

Graphene is a one-atom-thick layer of carbon atoms that is 200 times stronger than steel yet is extremely flexible and lighter than paper. It has almost always been known to be a good conductor of heat and electrical current but is notoriously difficult to handle. Experiments unlocking the puzzle of twisted bilayer graphene have been ongoing since MIT physicist Pablo Jarillo-Herrero and his group pioneered the emerging field of “twistronics” with their experiment in 2018 where they produced the graphene superconductor by twisting it to a magic angle of 1.1 degrees.

The Harvard scientists report successfully stacking three sheets of graphene and then twisting each of them at that magic angle to produce a three-layered structure that is not only capable of superconductivity but does so more robustly and at higher temperatures than many of the double-stacked graphene. The new and improved system is also sensitive to an externally applied electric field that allows them to tune the level of superconductivity by adjusting the strength of that field.

“It enabled us to observe the superconductor in a new dimension and provided us with important clues about the mechanism that’s driving the superconductivity,” said the study’s other lead author Zeyu Hao, a Ph.D. student in the Graduate School of Arts and Sciences also working in the Kim Group.

One of those mechanisms has the theorists really excited. The trilayer system showed evidence that its superconductivity is due to strong interactions between electrons as opposed to weak ones. If true, this can not only help open a path to high temperature superconductivity but possible applications in quantum computing.

“In most conventional superconductors, electrons move with a high speed and occasionally cross-paths and influence each other. In this case, we say their interaction effects are weak,” said Eslam Khalaf, a co-author on the study and postdoctoral fellow working in the lab of Harvard physics professor Ashvin Vishwanath. “While weakly interacting superconductors are fragile and lose superconductivity when heated to a few Kelvins, strong coupling superconductors are much more resilient but much less understood. Realizing strong coupling superconductivity in a simple and tunable system such as trilayer could pave the way to finally develop a theoretical understanding of strongly-coupled superconductors to help realize the goal of a high temperature, maybe even room temperature, superconductor.”

The researchers plan on continuing to explore the nature of this unusual superconductivity in further studies.

“The more we understand, the better we have chance to increase the superconducting transition temperatures,” said Kim.

Reference: “Electric field tunable superconductivity in alternating twist magic-angle trilayer graphene” by Zeyu Hao, A. M. Zimmerman, Patrick Ledwith, Eslam Khalaf, Danial Haie Najafabadi, Kenji Watanabe, Takashi Taniguchi, Ashvin Vishwanath and Philip Kim, 4 February 2021, Science.
DOI: 10.1126/science.abg0399

Funding: National science foundation, Department of Defense, Simons Collaboration on Ultra-Quantum Matter

4 Comments on "Harvard Scientists Trilayer Graphene Breakthrough Opens the Door for High Temperature Superconductors"

  1. Such a breakthrough is truly exciting as a potential enabling piece in the practical nuclear fusion puzzle, as well as other major human advances such as the quantum computing mentioned.

  2. Gürcan Aylanç | February 4, 2021 at 12:18 pm | Reply

    What about, newly discovered Boraphene, which has hundred times better properties than graphene? Is there any parallel study on it?

  3. you guys sound really smart, I am looking for smart and adventurous friends.

  4. I would like to visually see two comparative samples of the superconducting state compared to the resistive state.

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