Enzymes use cascade reactions to produce complex molecules from comparatively simple raw materials. Researchers have now copied this principle.
An international research team has used nanoparticles to convert carbon dioxide into valuable raw materials. Scientists at Ruhr-Universität Bochum in Germany and the University of New South Wales in Australia have adopted the principle from enzymes that produce complex molecules in multi-step reactions. The team transferred this mechanism to metallic nanoparticles, also known as nanozymes. The chemists used carbon dioxide to produce ethanol and propanol, which are common raw materials for the chemical industry.
The team led by Professor Wolfgang Schuhmann from the Center for Electrochemistry in Bochum and Professor Corina Andronescu from the University of Duisburg-Essen, together with the Australian team led by Professor Justin Gooding and Professor Richard Tilley, reported in the Journal of the American Chemical Society on August 25, 2019.
“Transferring the cascade reactions of the enzymes to catalytically active nanoparticles could be a decisive step in the design of catalysts,” says Wolfgang Schuhmann.
Particle with two active centers
Enzymes have different active centers for cascade reactions, which are specialized in certain reaction steps. For example, a single enzyme can produce a complex product from a relatively simple starting material. In order to imitate this concept, the researchers synthesized a particle with a silver core surrounded by a porous layer of copper. The silver core serves as the first active center, the copper layer as the second. Intermediate products formed at the silver core then react in the copper layer to form more complex molecules, which ultimately leave the particle.
In the present work, the German-Australian team showed that the electrochemical reduction of carbon dioxide can take place with the help of the nanozymes. Several reaction steps on the silver core and copper shell transform the starting material into ethanol or propanol.
“There are also other nanoparticles that can produce these products from CO2 without the cascade principle,” says Wolfgang Schuhmann. “However, they require considerably more energy.”
The researchers now want to further develop the concept of the cascade reaction in nanoparticles in order to be able to selectively produce even more valuable products such as ethylene or butanol.
Reference: “Cascade Reactions in Nanozymes: Spatially Separated Active Sites inside Ag-Core–Porous-Cu-Shell Nanoparticles for Multistep Carbon Dioxide Reduction to Higher Organic Molecules” by Peter B. O’Mara, Patrick Wilde, Tania M. Benedetti, Corina Andronescu, Soshan Cheong, J. Justin Gooding, Richard D. Tilley and Wolfgang Schuhmann, 25 August 2019, Journal of the American Chemical Society.
DOI: 10.1021/jacs.9b07310
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