Membrane filters don’t require much energy to purify water, making them popular for wastewater treatment. To keep these materials in tip-top condition, they’re commonly cleaned with large amounts of strong chemicals, but some of these agents destroy the membranes in the process. Now, researchers reporting in ACS Applied Materials & Interfaces have developed reusable nanoparticle catalysts that incorporate glucose to help efficiently break down contaminants inside these filters without damaging them.
Typically, dirty wastewater filters are unclogged with strong acids, bases, or oxidants. Chlorine-containing oxidants such as bleach can break down the most stubborn organic debris. But they also damage polyamide membranes, which are in most commercial nanofiltration systems, and they produce toxic byproducts. A milder alternative to bleach is hydrogen peroxide, but it decomposes contaminants slowly.
Previously, scientists have combined hydrogen peroxide with iron oxide to form hydroxyl radicals that improve hydrogen peroxide’s efficiency in a process known as the Fenton reaction. Yet in order for the Fenton reaction to clean filters, extra hydrogen peroxide and acid are needed, increasing financial and environmental costs. One way to avoid these additional chemicals is to use the enzyme glucose oxidase, which simultaneously forms hydrogen peroxide and gluconic acid from glucose and oxygen. So, Jianquan Luo and colleagues wanted to combine glucose oxidase and iron oxide nanoparticles into a system that catalyzes the Fenton-based breakdown of contaminants, creating an efficient and delicate cleaning system for membrane filters.
First, the researchers compared the removal of organic contaminants from polyamide filters by the glucose oxidase enzyme and iron oxide nanoparticles to other cleaning methods, including the traditional Fenton reaction. They found this approach was superior at breaking down the common contaminants bisphenol A and methylene blue, while also preserving more of the membrane structure.
Encouraged by their initial results, the team combined glucose oxidase and iron oxide into a single nanoparticle, connecting them with an amino bridge. Finally, they tested the new nanoparticle’s ability to clean methylene blue-soaked nanofiltration membranes, which they fouled and cleaned for three cycles. After each cleaning cycle, the nanoparticles were retrieved with a magnet and reused with fresh glucose to activate the catalyst.
The nanoparticles were highly effective at cleaning the membranes, returning them to 94% of their initial water filtration capacity. Because the nanoparticles don’t require strong chemicals and are easily recoverable, the researchers say their new system is a “greener” and more cost-effective approach for cleaning nanofiltration membranes.
Reference: “Chemoenzymatic Cascade Reaction for Green Cleaning of Polyamide Nanofiltration Membrane” by Jinxuan Zhang, Huiru Zhang, Yinhua Wan and Jianquan Luo, 2 March 2022, ACS Applied Materials & Interfaces.
The authors acknowledge funding from the Beijing Natural Science Foundation and the National Natural Science Foundation of China.
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