Expert-Defying Anomaly – Scientists Discover 2D Nanomaterial With Counter-Intuitive Expanding Properties

Blurry 2D Nanomaterial

Researchers have created tungsten semi-carbide nanosheets that expand against the direction of stretch, achieving a 40% increase in size. This breakthrough, achieved through plasma physics, promises new applications in strain-sensitive technologies and stretchable electronics. (Artist’s concept). Credit:

It is a common hack to stretch a balloon out to make it easier to inflate. When the balloon stretches, the width crosswise shrinks to the size of a string. Noah Stocek, a PhD student collaborating with Western University physicist Giovanni Fanchini, has developed a new nanomaterial that demonstrates the opposite of this phenomenon.

Working at Interface Science Western, home of the Tandetron Accelerator Facility, Stocek, and Fanchini formulated two-dimensional nanosheets of tungsten semi-carbide (or W2C, a chemical compound containing equal parts of tungsten and carbon atoms) which when stretched in one direction, expand perpendicular to the applied force. This structural design is known as auxetics.

Remote Plasma Vapour Deposition Instrument

Remote plasma vapor deposition instrument designed by Fanchini Lab. Credit: Mitch Zimmer/Western Science

The trick is that the structure of the nanosheet itself isn’t flat. The atoms in the sheet are made of repeating units consisting of two tungsten atoms to every carbon atom, which are arranged metaphorically like the dimpled surface of an egg carton. As tension is applied across the elastic nanosheet in one direction, it expands out in the other dimension as the dimples flatten.

Prior to this innovation, there has been only one reported material that could expand by 10 percent per unit length in this counter-intuitive way. The Western-engineered tungsten semi-carbide nanosheet can expand to 40 percent, a new world record.

“We were specifically looking to create a two-dimensional nanomaterial from tungsten semi-carbide,” said Stocek. “In 2018, theorists predicted that it might exhibit this behavior to an excellent level, but nobody had been able to develop it, despite extensive attempts by research groups all over the world.”

It wasn’t possible to construct the new tungsten semi-carbide nanomaterial using chemical means, so Stocek and Fanchini relied on plasma physics to form the single-atom layers. Made of charged particles of atoms, plasma is the fourth state of matter (with solid, liquid and gas). Plasma can be observed in the natural world in the northern lights, or Aurora Borealis, and the Sun’s corona during the recent solar eclipse. It is also used in neon lighting, fluorescent tubes, and flat-screen TVs.

Giovanni Fanchini and Noah Stocek

Giovanni Fanchini and Noah Stocek. Credit: Mitch Zimmer/Western Science

Typically, the instrumentation used to make two-dimensional nanomaterials are special furnaces where gases are heated at a high enough temperature to chemically react and form the desired substance. This approach simply did not work because any chemical reaction, the most common process, would lead to a product different from the desired nanomaterial.

“That’s where most researchers who tried to get this material before us got stuck, so we had to pivot,” said Fanchini.

Instead of heating a gas made of tungsten and carbon atoms in furnaces, which would produce neutral particles as you would get for solids, liquids or gases, Stocek and Fanchini designed a new customized instrumentation that produces a plasma, which is made up of electrically charged particles.

Noah Stocek

Western University PhD student Noah Stocek with the customized instrumentation he designed with Giovanni Fanchini that produces new record-setting two-dimensional nanomaterial. Credit: Mitch Zimmer/Western Science

Stretch goals

There are countless possible applications for these W2C nanosheets, beginning with a new type of strain gauge. These commercially available gauges are a standard way to measure expansion and stretch in everything from airplane wings to household plumbing.

“Imagine if you want to know if a pipe in your house is deforming and risks bursting at some point. You can stick a sensor on the pipe made from this two-dimensional nanomaterial, and then use a computer to monitor the current passing through it. If the current rises, it means the pipe is expanding and risks bursting,” said Stocek.

The new nanomaterial, in fact, becomes more electrically conductive and that opens the door for endless possibilities to use in things like sensors, or any device that detects events or changes in the environment and sends the information to other electronics. Another application is embedding the material right in stretchable electronics, like wearable technology, so that they have more conductivity.

“Normally, strain gauges would rely on the fact that when you stretch a material, it gets thinner and you change the conductivity of a material to carry a current,” said Fanchini. “With this new nanomaterial, this would no longer be the case.”

Reference: “Giant auxetic behavior in remote-plasma synthesized few-layer tungsten semicarbide” by Noah B. Stocek, Farman Ullah and Giovanni Fanchini, 8 April 2024, Materials Horizons.
DOI: 10.1039/D3MH02193A

Funding: NSERC DG, Ontario Graduate Scholarship, NSERC Strategic Partnership Grant, NSERC RTI, Canada Foundation for Innovation, Natural Sciences and Engineering Research Council of Canada

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