New Way To Generate Light Through Pre-Existing Defects in Semiconductor Materials

Indium-Rich Quantum Dot Fabrication

A new method of quantum dot fabrication has been demonstrated by making use of intrinsic defects in LED materials. Through the formation of pyramids, localized bright luminescence emanates from the pyramid apexes containing indium-rich quantum dots. Credit: SMART

The discovery demonstrates a practical method to overcome current challenges in the manufacture of indium gallium nitride (InGaN) LEDs with considerably higher indium concentration, through the formation of quantum dots that emit long-wavelength light.

  • The researchers have uncovered a new way to generate long-wavelength visible light by making use of intrinsic defects in light-emitting diodes (LEDs), which are used in a range of applications from general lighting to data communication and biological sensing
  • The new method provides an alternative approach to develop InGaN red light emitters, which traditionally suffer from poor efficiency
  • Following standard industry manufacturing procedures, this discovery can provide benefits through direct generation of red, green and blue light in commercial full-colour light sources and displays

Researchers from the Low Energy Electronic Systems (LEES) Interdisciplinary Research Group (IRG) at Singapore-MIT Alliance for Research and Technology (SMART), MIT’s research enterprise in Singapore, together with collaborators at the Massachusetts Institute of Technology (MIT), National University of Singapore (NUS) and Nanyang Technological University (NTU) have discovered a new method of generating long-wavelength (red, orange, and yellow) light through the use of intrinsic defects in semiconducting materials, with potential applications as direct light emitters in commercial light sources and displays. This technology would be an improvement on current methods, which use phosphors, for instance, to convert one colour of light to another.

A type of group-III element nitride-based light-emitting diode (LED), indium gallium nitride (InGaN) LEDs were first fabricated over two decades ago in the 90s, and have since evolved to become ever smaller while growing increasingly powerful, efficient, and durable. Today, InGaN LEDs can be found across a myriad of industrial and consumer use cases, including signals & optical communication and data storage – and are critical in high-demand consumer applications such as solid state lighting, television sets, laptops, mobile devices, augmented (AR) and virtual reality (VR) solutions.

Ever-growing demand for such electronic devices has driven over two decades of research into achieving higher optical output, reliability, longevity and versatility from semiconductors – leading to the need for LEDs that can emit different colors of light. Traditionally, InGaN material has been used in modern LEDs to generate purple and blue light, with aluminum gallium indium phosphide (AlGaInP) – a different type of semiconductor – used to generate red, orange, and yellow light. This is due to InGaN’s poor performance in the red and amber spectrum caused by a reduction in efficiency as a result of higher levels of indium required.

In addition, such InGaN LEDs with considerably high indium concentrations remain difficult to manufacture using conventional semiconductor structures. As such, the realization of fully solid-state white-light-emitting devices – which require all three primary colors of light – remains an unattained goal.

Addressing these challenges, SMART researchers have laid out their findings in a paper titled “Light-Emitting V-Pits: An Alternative Approach toward Luminescent Indium-Rich InGaN Quantum Dots”, recently published in the journal ACS Photonics. In their paper, the researchers describe a practical method to fabricate InGaN quantum dots with significantly higher indium concentration by making use of pre-existing defects in InGaN materials.

In this process, the coalescence of so-called V-pits, which result from naturally-existing dislocations in the material, directly forms indium-rich quantum dots, small islands of material that emit longer-wavelength light. By growing these structures on conventional silicon substrates, the need for patterning or unconventional substrates is further eliminated. The researchers also conducted high spatially-resolved compositional mapping of the InGaN quantum dots, providing the first visual confirmation of their morphology.

In addition to the formation of quantum dots, the nucleation of stacking faults – another intrinsic crystal defect – further contributes to emissions of longer wavelengths.

Jing-Yang Chung, SMART graduate student and lead author of the paper said, “For years, researchers in the field have attempted to tackle the various challenges presented by inherent defects in InGaN quantum well structures. In a novel approach, we instead engineered a nano-pit defect to achieve a platform for direct InGaN quantum dot growth. As a result, our work demonstrates the viability of using silicon substrates for new indium-rich structures, which along with addressing current challenges in the low efficiencies of long-wavelength InGaN light emitters, also alleviate the issue of expensive substrates.”

In this way, SMART’s discovery represents a significant step forward in overcoming InGaN’s reduced efficiency when producing red, orange, and yellow light. In turn, this work could be instrumental in the future development of micro LED arrays consisting of a single material.

Dr. Silvija Gradečak, co-author and Principal Investigator at LEES, added, “Our discovery also has implications for the environment. For instance, this breakthrough could lead to a more rapid phasing out of non-solid-state lighting sources – such as incandescent bulbs – and even the current phosphor-coated blue InGaN LEDs with a fully solid-state color-mixing solution, in turn leading to a significant reduction in global energy consumption.”

“Our work could also have broader implications for the semiconductor and electronics industry, as the new method described here follows standard industry manufacturing procedures and can be widely adopted and implemented at scale,” said SMART CEO and LEES Lead Principal Investigator Eugene Fitzgerald. “On a more macro level, apart from the potential ecological benefits that could result from InGaN-driven energy savings, our discovery will also contribute to the field’s continued research into and development of new efficient InGaN structures.”

Reference: “Light-Emitting V-Pits: An Alternative Approach toward Luminescent Indium-Rich InGaN Quantum Dots” by Jing-Yang Chung, Zhang Li, Sarah A. Goodman, Jinkyu So, Govindo J. Syaranamual, Tara P. Mishra, Eugene A. Fitzgerald, Michel Bosman, Kenneth Lee, Stephen J. Pennycook and Silvija Gradečak, 10 September 2021, ACS Photonics.
DOI: 10.1021/acsphotonics.1c01009

The research is carried out by SMART and supported by the National Research Foundation (NRF) Singapore under its Campus for Research Excellence and Technological Enterprise (CREATE) program. For this paper, the LED structures were grown using SMART’s unique facilities and know-how, structural studies were conducted at NUS using state-of-the-art, atomically-resolved electron microscopes, while nanoscale optical studies were conducted at MIT and NTU.

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