Researchers have developed a method, called inverse thermal degradation (ITD), to control how flames interact with materials using a nanoscale protective layer. This allows precise tuning of the processed material’s properties, demonstrated by creating microscale carbon tubes from cellulose fibers.
High-temperature flames are essential for producing numerous materials. However, controlling a fire and its interaction with the intended material can be challenging. Scientists have now developed a method that employs a molecule-thin protective layer to control how the flame’s heat interacts with the material – taming the fire and allowing users to finely tune the characteristics of the processed material.
“Fire is a valuable engineering tool – after all, a blast furnace is only an intense fire,” says Martin Thuo, corresponding author of a paper on the work and a professor of materials science and engineering at North Carolina State University. “However, once you start a fire, you often have little control over how it behaves.
“Our technique, which we call inverse thermal degradation (ITD), employs a nanoscale thin film over a targeted material. The thin film changes in response to the heat of the fire and regulates the amount of oxygen that can access the material. That means we can control the rate at which the material heats up – which, in turn, influences the chemical reactions taking place within the material. Basically, we can fine-tune how and where the fire changes the material.”
Here’s how ITD works. You start out with your target material, such as a cellulose fiber. That fiber is then coated with a nanometer-thick layer of molecules. The coated fibers are then exposed to an intense flame. The outer surface of the molecules combusts easily, raising the temperature in the immediate vicinity. But the inner surface of the molecular coating chemically changes, creating an even thinner layer of glass around the cellulose fibers. This glass limits the amount of oxygen that can access the fibers, preventing the cellulose from bursting into flames. Instead, the fibers smolder – burning slowly, from the inside out.
“Without the ITD’s protective layer, applying flame to cellulose fibers would just result in ash,” Thuo says. “With the ITD’s protective layer, you end up with carbon tubes.
“We can engineer the protective layer in order to tune the amount of oxygen that reaches the target material. And we can engineer the target material in order to produce desirable characteristics.”
The researchers conducted proof-of-concept demonstrations with cellulose fibers to produce microscale carbon tubes.
The researchers could control the thickness of the carbon tube walls by controlling the size of the cellulose fibers they started with; by introducing various salts to the fibers (which further controls the rate of burning); and by varying the amount of oxygen that passes through the protective layer.
“We have several applications in mind already, which we will be addressing in future studies,” Thuo says. “We’re also open to working with the private sector to explore various practical uses, such as developing engineered carbon tubes for oil-water separation – which would be useful for both industrial applications and environmental remediation.”
Reference: “Spatially Directed Pyrolysis via Thermally Morphing Surface Adducts” by Chuanshen Du, Paul Gregory, Dhanush U. Jamadgni, Alana M. Pauls, Julia J. Chang, Rick W. Dorn, Andrew Martin, E. Johan Foster, Aaron J. Rossini and Martin Thuo, 19 July 2023, Angewandte Chemie.
DOI: 10.1002/anie.202308822
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