Encapsulating multiple molecular catalysts in nanoporous metal-organic frameworks central to efficient transformation.
Converting carbon dioxide to methanol, a potentially renewable alternative fuel, offers an opportunity to simultaneously form an alternative fuel and cut down on carbon dioxide emissions.
Inspired by naturally occurring processes, a team of Boston College chemists used a multi-catalyst system to convert carbon dioxide to methanol at the lowest temperatures reported with high activity and selectivity, the researchers reported in a recent online edition of the journal Chem.
The team’s discovery was made possible by installing multiple catalysts in a single system constructed within a sponge-like porous crystalline material known as a metal-organic framework, said Boston College Associate Professors of Chemistry Jeffery Byers and Frank Tsung, lead authors of the report.
Held in place by the sponge, the separate catalysts work in harmony. Without isolation of the catalytically active species in this way, the reaction did not proceed and no product was obtained, they reported.
The team drew its inspiration from the biological machinery in cells, which use multicomponent chemical reactions with great efficiency, Tsung said.
The team employed catalyst separation through host-guest chemistry — where a “guest” molecule is encapsulated in a “host” material to form a new chemical compound — in order to convert carbon dioxide to methanol. The approach, inspired by the multicomponent catalytic transformations in nature, converted a greenhouse gas to a renewable fuel while avoiding high catalytic demand on a single species.
“We accomplished this by encapsulating one or more catalysts in metal-organic framework and applying the resulting host-guest construct in catalysis in tandem with another transition metal complex,” said Tsung.
The team, which included graduate student Thomas M. Rayder and undergraduate Enric H. Adillon, set out to determine whether they could develop an approach to integrate incompatible catalysts in order to convert carbon dioxide to methanol at low temperature and with high selectivity, said Byers.
Specifically, they wanted to find out if there are specific advantages to this approach when compared to current state of the art systems for transition metal complex-based conversion of carbon dioxide to methanol.
“Positioning multiple transition metal complex catalysts at the right position in a system is critical to the reaction turning over,” said Byers. “At the same time, encapsulating these catalysts allowed for recyclability in the multicomponent catalytic system.”
These properties make the multicomponent catalyst construct more industrially relevant, which may pave the way for a carbon-neutral fuel economy, the researches said.
In addition to achieving site isolation by encapsulating the catalysts, which led to catalyst activity and recyclability, the team discovered an autocatalytic feature of the catalyst that enabled the reaction to be run without the need for large amounts of additives. Most previous reports for similar reactions use large amounts of additives, but the team’s approach avoids this necessity and it is the first to use carbon dioxide in an energy-related reaction, Tsung said.
The team plans to do further research into the modularity of both the encapsulation method and the metal-organic frameworks to gain a deeper understanding of the multicomponent system and optimize it further, as well as access new, unexplored reactivity through the formation of new host-guest constructs, Tsung said.
Reference: “A Bioinspired Multicomponent Catalytic System for Converting Carbon Dioxide into Methanol Autocatalytically” by Thomas M. Rayder, Enric H. Adillon, Jeffery A. Byers and Chia-Kuang Tsung, 5 May 2020, Chem.
And what happens when you spill methanol into a river or lake?
What does happen? Doesnt it just get the fish drunk?
Just wondering ,Falter is that you litte dragon?