Nanotech Scientists Created Something Unexpected: Tiny Metallic Snowflakes

Nano Particle Metallic Snowflakes

Nano-scale snowflake from Gallium solvent. Credit: Waipapa Taumata Rau, University of Auckland

Adventures in Nanotech: Growing a Metallic Snowflake

Scientists working at the level of atoms are manipulating metals, opening up possibilities for creating new materials.

Working at the level of atoms, scientists in New Zealand and Australia created something unexpected: tiny metallic snowflakes.

Why’s that significant? Because coaxing individual atoms to cooperate is leading to a revolution in engineering and technology via nanomaterials. (And creating snowflakes is cool.)

Nanoscale structures (a nanometer is one billionth of a meter or about 50,000 times smaller than the diameter of a human hair) can aid electronic manufacturing, make materials stronger yet lighter, or aid environmental clean-ups by binding to toxins.

To create metallic nanocrystals, New Zealand and Australian scientists have been conducting experiments with gallium, a soft, silvery metal that is used in semiconductors and has the unusual property of liquifying at slightly above room temperature.

Their results were reported on December 8 in the journal Science.

Professor Nicola Gaston and research fellow Dr. Steph Lambie, both of Waipapa Taumata Rau, University of Auckland, and Dr. Krista Steenbergen of Te Herenga Waka, Victoria University of Wellington, collaborated with colleagues in Australia led by Professor Kourosh Kalantar-Zadeh at the University of New South Wales.

The Australian team worked in the lab with nickel, copper, zinc, tin, platinum, bismuth, silver, and aluminum. Metals were dissolved in gallium at high temperatures. Once cooled, the metallic crystals emerged while the gallium remained liquid.

Growing Metallic Snowflake

Credit: University of Auckland

The New Zealand team, part of the MacDiarmid Institute for Advanced Materials and Nanotechnology, a national Centre of Research Excellence, carried out simulations of molecular dynamics to explain why differently shaped crystals emerge from different metals. (The government’s Marsden Fund supported the research.)

“What we are learning is that the structure of the liquid gallium is very important,” says Gaston. “That’s novel because we usually think of liquids as lacking structure or being only randomly structured.”

Interactions between the atomistic structures of the different metals and the liquid gallium cause differently shaped crystals to emerge, the scientists showed.

The crystals included cubes, rods, hexagonal plates, and the zinc snowflake shapes. The six-branched symmetry of zinc, with each atom surrounded by six neighbors at equivalent distances, accounts for the snowflake design.

“In contrast to top-down approaches to forming nanostructure – by cutting away material – this bottom-up approach relies on atoms self-assembling,” says Gaston. “This is how nature makes nanoparticles, and is both less wasteful and much more precise than top-down methods.”

She says the research has opened up a new, unexplored pathway for metallic nanostructures. “There’s also something very cool in creating a metallic snowflake!”

Reference: “Liquid metal synthesis solvents for metallic crystals” by Shuhada A. Idrus-Saidi, Jianbo Tang, Stephanie Lambie, Jialuo Han, Mohannad Mayyas, Mohammad B. Ghasemian, Francois-Marie Allioux, Shengxiang Cai, Pramod Koshy, Peyman Mostaghimi, Krista G. Steenbergen, Amanda S. Barnard, Torben Daeneke, Nicola Gaston and Kourosh Kalantar-Zadeh, 8 December 2022, Science.
DOI: 10.1126/science.abm2731

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