Chinese Scientists Develop a High-Performance Ultralong-Life Aqueous Zinc-Ion Battery

Breakthrough in Zinc-Ion Battery Technology Paves the Way for Improved Energy Storage Solutions

A research team at the Hefei Institutes of Physical Science (HFIPS) of Chinese Academy of Sciences (CAS), led by Prof. Zhao Bangchuan, developed a high-performance aqueous zinc-ion battery with ultralong cycle lifespan in a weak magnetic field.

The findings were recently published in the journal Materials Horizons.

Aqueous zinc-ion batteries are a low-cost and safe alternative to lithium-ion batteries with high theoretical capacity. However, the limited electrochemical performance of cathode material and zinc dendrite growth on the anode reduces the energy density and cycle life of an aqueous zinc-ion battery. To develop better aqueous zinc-ion batteries, it’s important to design high-energy-density cathodes and suppress zinc dendrite growth.

Innovative Cathode Design for Enhanced Performance

In this research, the team overcame the limitations of existing cathode materials and the issue of zinc dendrite growth. They used a one-step hydrothermal method with in-situ electrochemical defect engineering to create a VS₂ material. This material had rich defects that were effective in reducing the electrostatic interaction between zinc ions and VS₂. It allowed for 3D transport of Zn²⁺ along both the ab plane and c-axis, resulting in excellent rate capability.

While cycling stability remained an issue due to the dendrite growth, the team found that introducing an external magnetic field suppressed the growth and significantly enhanced the battery’s lifespan. Operating under a weak magnetic field, the high-performance Zn-VS₂ battery demonstrated an ultralong cycle lifespan and delivered a high energy density and power density.

The work could have significant implications for the future of energy storage technology, according to the team.

Reference: “Magneto-electrochemistry driven ultralong-life Zn-VS2 aqueous zinc-ion batteries” by Yunjie Mao, Jin Bai, Jianguo Si, Hongyang Ma, Wanyun Li, Peiyao Wang, Hongli Zhang, Zhigao Sheng, Xiaoguang Zhu, Peng Tong, Xuebin Zhu, Bangchuan Zhao and Yuping Sun, 19 May 2023, Materials Horizons.
DOI: 10.1039/D3MH00303E

Never miss a breakthrough: Join the SciTechDaily newsletter.
Follow us on Google and Google News.