When stretched or deformed, shape memory polymers return to their original shapes after heat or light is applied. These materials show great promise for soft robotics, smart biomedical devices and deployable space structures, but until now they haven’t been able to store enough energy. Now, researchers reporting in ACS Central Science have developed a shape memory polymer that stores almost six times more energy than previous versions.
Shape memory polymers alternate between an original, undeformed state and a secondary, deformed state. The deformed state is created by stretching the polymer and is held in place by molecular changes, such as dynamic bonding networks or strain-induced crystallization, that are reversed with heat or light. The polymer then returns to its original state through the release of stored entropic energy. But it’s been challenging for scientists to make these polymers perform energy-intensive tasks. Zhenan Bao and colleagues wanted to develop a new type of shape memory polymer that stretches into a stable, highly elongated state, allowing it to release large amounts of energy when returning to its original state.
The researchers incorporated 4-,4’-methylene bisphenylurea units into a poly(propylene glycol) polymer backbone. In the polymer’s original state, polymer chains were tangled and disordered. Stretching caused the chains to align and form hydrogen bonds between urea groups, creating supermolecular structures that stabilized the highly elongated state. Heating caused the bonds to break and the polymer to contract to its initial, disordered state.
In tests, the polymer could be stretched up to five times its original length and store up to 17.9 J/g energy –– almost six times more energy than previous shape memory polymers. The team demonstrated that the stretched material could use this energy to lift objects 5,000 times its own weight upon heating. They also made an artificial muscle by attaching the pre-stretched polymer to the upper and lower arm of a wooden mannequin. When heated, the material contracted, causing the mannequin to bend its arm at the elbow. In addition to its record-high energy density, the shape memory polymer is also inexpensive (raw materials cost about $11 per lb) and easy to make, the researchers say.
Reference: “High Energy Density Shape Memory Polymers Using Strain-Induced Supramolecular Nanostructures” by Christopher B. Cooper, Shayla Nikzad, Hongping Yan, Yuto Ochiai, Jian-Cheng Lai, Zhiao Yu, Gan Chen, Jiheong Kang and Zhenan Bao, 8 September 2021, ACS Central Science.
The authors acknowledge funding from the U.S. Department of Defense, the National Science Foundation and the U.S. Department of Energy.